Kinetic resolution: a powerful tool for the synthesis of planar-chiral ferrocenes.
نویسندگان
چکیده
Since the serendipitous discovery of ferrocene by Pauson and Kealy in 1951, it has become one of the most important structures in Organic Chemistry. Lately, kinetic resolution has emerged as a useful tool for the synthesis of planar chiral ferrocenes. This review aims to cover and discuss the development of this topic.
منابع مشابه
Enantioselective synthesis of planar chiral ferrocenes via palladium-catalyzed annulation with diarylethynes
When Boc-L-Val-OH was used as a ligand for the enantioselective Pd(II)-catalyzed annulation of N,N-substituted aminomethyl ferrocene derivatives with diarylethynes, ferrocenes with planar chirality could be achieved with excellent enantioselectivity (up to 99% ee).
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عنوان ژورنال:
- Molecules
دوره 14 11 شماره
صفحات -
تاریخ انتشار 2009